No, you can use anything only in one PayPal account. So, better stay with one account or make one with another name of your family who is having all things needed in PP.
Does it make any sense with same identification, you want two a/c? You can use one of your family member for creating PayPal a/c because even if PAN will work, later you would be adding bank a/c otherwise what would be use of creating a/c if you can attach a bank a/c?
No you wont be able to link same pan card for two accounts so its not good may be if you try then they will ban you
Try once , you will get massage "this pan card already attached with other account please use another pan card" i don't know why users ask such type question , Even 99% of thread openers had tried it before asking .
You can open two accounts in paypal using personal and premier account with your single name but you must need to use different pan card for it ...because it will never work if your using one pan card