For selection of the Title of your website please check out the keyword competition, monthly searches. Then check out that how properly set out or map out that keyword within the content of the page. After that place out your targeted keyword or key phrases within the title tag with the amount of 60 characters maximum.
There are many free keywords tool available online like; Google Adwords, Free word Tracker, Keyword Discovery, Keywordspy and etc. Where you can analyze your keywords and get more likable keywords for your website title.
I have read you want the <H1> (first heading) to have your title somewhere in it. I think the closer the better. I usually do Keyword Phrase- Whatever Title I want. I would put it in your <H2> (second) headings as well.
Try to get a nice URL that goes well with the title - for example: www maltacardealer com - Title: Malta Car Dealer <H1> Malta Used Cars Dealer, etc.......
Use your site main and high searches keywords in title. And other's in meta description. Because title define that what your site about.
Normally first keywords should appear in first para of your web page. Even in title and H1 tag can be your primary keyword.
I use the keywords as the page title,Homepage use your target keywords ,Content pages use long tail keywords.
You can use Google keyword tool and first search best keyword for your website which should be fully relevant then set title of your website.