If your want create static website Dream weaver is best and if you want create dynamic website with many pages word press is a best way to do it.
User Dreamwaver to create static website ? You fail Dreamwaver was born to be used as a dynamic website development tool
dynamic website is that we should develop a coding in php or asp to generate a new page dynamically is known as dynamic website
I didn't tell that Dream weaver can only develop static website you can also develop dynamic website for that we should develop a coding but in word press we don't need to develop any coding Because word press is already have developed word press themes so that our work will be simple.
try Adobe Photoshop + Dreamweaver or Corel Draw + Corel Paint + Dreamweaver. You do the designing in Adobe Photoshop or Corel then you slice it there then do some editing and cleaning in DreamWeaver. Goodluck and have fun!
but in wordpress you have to work with something already made... DW you create your own think.. but also depends on the purpose..
If you want to create a website (fast) try to use Wordpress. If you don't know PHP, don't even think about using Dreamweaver, as you can only create static webpages in it (without coding).