I am looking for a design company to do some experience with, I want to learn Photoshop and HTML, CSS etc. I have a little knowledge but I want to gain more.
That depends. If he is wanting to learn PS and just general HTML/CSS for a design career then he doesn't need to worry about those, if it's for a web design career then he will most probably want to. But take it in steps. HTML/CSS before any other languages like PHP or JavaScript.